Methanol-to-Olefin Conversion over UZM-9 Zeolite: Effect of Transition Metal Ion Exchange on its Deactivation
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چکیده
منابع مشابه
Effect of Feedstock and Catalyst Impurities on the Methanol‐to‐Olefin Reaction over H‐SAPO‐34
Operando UV/Vis spectroscopy with on-line mass spectrometry was used to study the effect of different types of impurities on the hydrocarbon pool species and the activity of H-SAPO-34 as a methanol-to-olefins (MTO) catalyst. Successive reaction cycles with different purity feedstocks were studied, with an intermittent regeneration step. The combined study of two distinct impurity types (i.e., f...
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Shape-selective methylation of naphthalene (NAPH) over SAPO-11 zeolite was carried out in a fixed-bed flow reactor under atmospheric pressure. Some zeolites, such as H-beta (Hβ), HUSY and ZSM-5 were also evaluated for comparison with SAPO-11 zeolite.The results showed that SAPO-11 exhibited higher stability, higher selectivity of 2,6-dimethylnaphthalene (2,6-DMN), and higher 2,6-/2,7-DMN r...
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متن کاملDirect observation of hexamethylbenzenium radical cations generated during zeolite methanol-to-olefin catalysis: an ESR study.
The generation of hexamethylbenzenium radical cations as the key reaction intermediate in chabazite-type molecular sieve acids (i.e., H-SAPO-34 and H-SSZ-13) during the methanol-to-olefin process has been directly evidenced by ESR spectroscopy.
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ژورنال
عنوان ژورنال: Korean Chemical Engineering Research
سال: 2013
ISSN: 0304-128X
DOI: 10.9713/kcer.2013.51.2.181